view . fall 2012
        
        
          5
        
        
          
            Have you ever thought about what happens after someone
          
        
        
          
            flushes unused medications down the toilet?
          
        
        
          Rajesh Seth has
        
        
          done just that.
        
        
          A professor in civil and environmental engineering,
        
        
          Dr. Seth studies levels of potentially harmful chemicals including
        
        
          pharmaceuticals and personal care products (PPCPs) being found
        
        
          in treated wastewater, and more
        
        
          importantly, what to do about them.
        
        
          “I don’t want to set off alarm
        
        
          bells, but these are being found in low
        
        
          concentrations,” he says. “There is
        
        
          concern about them being frequently
        
        
          detected and what their possible effects
        
        
          might be.”
        
        
          At least 80 PPCPs including
        
        
          antibiotics, antidepressants, and blood
        
        
          lipid regulators have been identified in
        
        
          outflows from wastewater treatment
        
        
          plants worldwide, according to a 2007
        
        
          Environment Canada report. Closer to
        
        
          home, Seth co-authored a study that
        
        
          reported 14 of 51 targeted chemicals
        
        
          were consistently found in samples of discharge water from a local
        
        
          sewage treatment plant which empties into the Detroit River.
        
        
          Part of the problem is people’s indifference to disposing of a
        
        
          variety of products, according to Chris Manzon BASc ’90, MASc ’00,
        
        
          plant manager at the Little River Pollution Control plant where
        
        
          Seth’s team is conducting its research.
        
        
          “The toilet is not a garbage can,” says Manzon. “These
        
        
          chemicals go somewhere when you flush them.”
        
        
          There is emerging concern in the scientific community about
        
        
          endocrine-disrupting chemicals found in PPCPs and their potential
        
        
          to harm human hormonal systems.
        
        
          Seth is studying the use of ozone to remove them from
        
        
          wastewater after it’s treated. It’s a method already used to treat
        
        
          drinking water at the A.H. Weeks Water Treatment Plant, which
        
        
          distributes up to 349 million litres of water to Windsor residents
        
        
          each day. Seth believes drinking water would be further protected
        
        
          if there were better methods of treating wastewater before it gets
        
        
          dumped into the ecosystem and makes its way back to drinking
        
        
          water intakes that treatment plants rely on.
        
        
          “It just made more sense to remove those chemicals at the
        
        
          source,” he says.
        
        
          Manzon says the plant’s conventional sludge-activated system—
        
        
          which relies on microbial processes and UV light to eliminate
        
        
          contaminants—removes about 98 per cent of such harmful
        
        
          materials as human waste, nutrients and pathogens from the 45
        
        
          million litres of wastewater it treats
        
        
          every day, but isn’t equipped to deal
        
        
          with chemicals found in PPCPs.
        
        
          “We do a good job of getting most
        
        
          of the stuff out, but this technology is
        
        
          100 years old,” he explains.
        
        
          At the plant, Seth and his team
        
        
          of graduate students set up a mobile
        
        
          research station. Pure oxygen runs
        
        
          through a generator to produce
        
        
          ozone, a pale blue gas made up of
        
        
          three oxygen atoms that smells like
        
        
          chlorine. That ozone is diffused in
        
        
          a bubbling column of water already
        
        
          treated by the plant. Another column
        
        
          contains the un-ozonated water, and
        
        
          researchers compare the two.
        
        
          Master’s student Saileshkumar Singh said the method is
        
        
          removing chemicals at a rate of about 80 per cent.
        
        
          “It’s been very effective for both disinfection and for removal of
        
        
          contaminants of concern,” he says.
        
        
          The process, however, does create some by-products, so
        
        
          fellow student Mike Reaume is working on a follow-up biological
        
        
          treatment to address them. If they can be overcome, Singh says he
        
        
          hopes ozone will be widely implemented as a method of treating
        
        
          wastewater: “I think Canada is a country that’s been a world leader
        
        
          in wastewater treatment and at implementing new processes.”
        
        
          For the time being, Manzon is happy to have the researchers
        
        
          in his plant testing its effectiveness. “We really don’t know what
        
        
          the long term effect of these chemicals might be,” he says. “The
        
        
          University has had a long history of doing pilot studies with us here
        
        
          and at other facilities. When they have something they’d like to
        
        
          try, we like to be here for them. Down the road, it may be of some
        
        
          benefit to the facility.”
        
        
          n
        
        
          
            v
          
        
        
          REDUCING THE H
        
        
          2
        
        
          O
        
        
          CHEMICAL EQUATION
        
        
          
            Drugs in the water
          
        
        
          “The toilet is not a garbage
        
        
          can, These chemicals go
        
        
          somewhere when you flush
        
        
          them... We do a good job of
        
        
          getting most of the stuff
        
        
          out, but this technology is
        
        
          100 years old.”
        
        
          
            Chris Manzon
          
        
        
          
            BASc ’90, MASc ’00
          
        
        
          RESEARCH
        
        
          BY STEPHEN FIELDS